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Captodative Olefins: Methyl 2-Aryloxy-3-dimethylaminopropenoates and Their Application in a New Synthesis of Benzofurans.

✍ Scribed by Maria del Carmen Cruz; Joaquin Tamariz


Book ID
101954068
Publisher
John Wiley and Sons
Year
2004
Weight
98 KB
Volume
35
Category
Article
ISSN
0931-7597

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## Abstract Methyl (Z)‐2‐acetylamino‐3‐dimethylaminopropenoate (3) was prepared from __N__‐acetylglycine (1), which was converted with __N,N__‐dimethylformamide and phosphorus oxychloride into 4‐dimethylaminomethylene‐2‐methyl‐5(4__H__)‐oxazolone (2), followed by treatment with methanol in the pres