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Capillary electrophoretic and computational study of the complexation of valinomycin with rubidium cation

✍ Scribed by Sille Ehala; Jiří Dybal; Emanuel Makrlík; Václav Kašička

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
348 KB
Volume
30
Category
Article
ISSN
0173-0835

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Reactions of laser-desorbed Na(+), K(+), Rb(+), and Cs(+) with thermally vaporized valinomycin generate metal-ligand complexes in a Fourier transform ion cyclotron resonance trapping cell, proving that complexes can form via gas-phase ion-molecule reactions. Although desorption of intact pre-formed