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Camphor-Palladium Complexes as Catalysts for Cyclization of Alkynes

✍ Scribed by Carvalho, M. Fernanda N. N.; Duarte, M. Teresa; Herrmann, Rudolf


Book ID
120878508
Publisher
UOCHB
Year
2006
Tongue
English
Weight
149 KB
Volume
71
Category
Article
ISSN
0010-0765

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In the presence of methanesulfonic acid, the palladium(0)-olefin complexes: [Pd( 2 -ol)(P-N)] [ol = dimethyl fumarate or fumaronitrile, P-N = 1-(Ph 2 P)C 6 H 4 -2-CH=NR (R = CMe 3 or C 6 H 4 OMe-4)] catalyse the alkoxycarbonylation of terminal alkynes. Moderately good rates are obtained when the cat