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Calyculins. Asymmetric synthesis of the C26-C32 fragment

✍ Scribed by Ari M.P. Koskinen; Petri M. Pihko

Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
263 KB
Volume
35
Category
Article
ISSN
0040-4039

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Asymmetric Synthesis of Calyculin C. Part 2. Synthesis of the C26-C37 Fragment and Model Wittig Couplings. -The C26-C37 fragment (VIII) of the serine/threonine phosphatase inhibitor calyculin C is synthesized by coupling of the C33-C37 aza-sugar (II) with the C26-C32-aminooxazole (VI). The phosphoni