Calorimetric determination of the hydrogen bond enthalpy of some alcohols

✍ Scribed by Alfred Kolbe; Carsta Zimmermann; Rainer Wilke

• Publisher: Elsevier Science
• Year: 1981
• Weight: 498 KB
• Volume: 19
• Category: Article
• ISSN: 0378-4487
• DOI: 10.1016/0378-4487(81)80034-9

✦ Synopsis

The heat of dilution to infinite dilution of solutions of trans (I) and cis I-t-butylcyclohexan-4-01 (II) as well as t-butsnol (III) and cis-para-menthanol-4 (IV) in Ccl4 were investigated by ampoule calorimetry at 15' and 30' C. During this dibutlon all the hydrogen bonds due to the homoassoclation of these aloohols are broken, as has been checked by ir spectroscopy. The heat