Calix[4]arene-constrained cyclopeptides, a novel type of macrocyclic host molecule
โ Scribed by Xubo Hu; Albert S.C. Chan; Xinxin Han; Jiaqi He; Jin-Pei Cheng
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 257 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Two calix [4]arene cyclopeptides were synthesized by reacting 1,3-di(chlorocarbonyi-methoxy)-p-tert-butylca|ix[4]arene with cystine dimethyl ester dihydrochioride. One of them was found to be a good receptor for phosphomonoester.
๐ SIMILAR VOLUMES
Calix[4 ]arenes 1 and 2, functionalised on their upper rim with amidopyridine groups, have been synthesised. In the case of 1, a detailed binding study with a range of aliphatic and aromatic dicarboxylic acids has been carried out using 1 H NMR spectroscopy. The binding affinities are largely depen
## Abstract The structure and dynamics of the dichloromethane solvent around the calix[4]arene units contained in the molecular actuator poly(calix[4]arene bisโbithiophene) have been examined using a 1โฮผs molecular dynamics simulation. Results indicate that a solvent molecule fills the cavity assoc