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Calix[4]arene-constrained cyclopeptides, a novel type of macrocyclic host molecule

โœ Scribed by Xubo Hu; Albert S.C. Chan; Xinxin Han; Jiaqi He; Jin-Pei Cheng


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
257 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Two calix [4]arene cyclopeptides were synthesized by reacting 1,3-di(chlorocarbonyi-methoxy)-p-tert-butylca|ix[4]arene with cystine dimethyl ester dihydrochioride. One of them was found to be a good receptor for phosphomonoester.


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## Abstract The structure and dynamics of the dichloromethane solvent around the calix[4]arene units contained in the molecular actuator poly(calix[4]arene bisโ€bithiophene) have been examined using a 1โ€ฮผs molecular dynamics simulation. Results indicate that a solvent molecule fills the cavity assoc