Mass spectra of synthetic porphyrins were recorded using a 252Cf Time-of-flight mass spectrometer (TOF 21). They proved to be very useful for obtaining structure probes on porphyrins for which very little information was available owing to the presence of paramagnetic ions or to badly resolved NMR s
Californium-252 Time-of-flight Mass Spectrometry of Monometallic and Bimetallic Ruthenium(II) Complexes
β Scribed by Isabelle Sasaki; Claude Deprun; Alain Gaudemer
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 413 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0951-4198
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β¦ Synopsis
Mass spectra of monometallic and bimetallic ruthenium(I1) complexes were recorded using a "'Cf time-of-flight mass spectrometer. They proved to be useful for obtaining structural information relating to these complexes. Moreover, they confirmed the nature of the environment around the metal center.
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