Calibration method in isotopic carbon analysis
β Scribed by Zhang Weicheng; Li Liwu
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 227 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0883-2889
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β¦ Synopsis
Unlike neutrons or gamma-rays, charged particles readily lose energy when they penetrate matter; thus, the main difficulty in its calculation is, perhaps, the complication introduced in its mathematical treatment.
In our experiments, determination of ~3C in breath test samples by proton-induced gamma-ray emission, interesting regularities were found that allowed drastic simplification in the theoretical treatment of the problem, and led to the derivation from first principles of a simple, sufficiently accurate basic equation which proved reliable for the determination of the isotopic abundance ratio ~3C/J2C by low-energy proton bombardment of biological samples with simultaneous prompt gamma spectrometry.
π SIMILAR VOLUMES
A m d i e d method for the carbon and oxygen isotope analysis of 'small samples' (<lo0 pg) of common, naturally occurring carbonate minerals (calcite, dolomite, siderite) using conventional phosphoric acid digestion techniques is described. Samples are reacted in vacuo with ca. 30 pL of anhydrous ac