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Calculations of the Equilibrium Isotope Effects on the Reductions of Benzene- d 6 and Cyclooctatetraene- d 8

โœ Scribed by Hrovat, David A.; Hammons, J. H.; Stevenson, Cheryl D.; Borden, Weston Thatcher

Book ID
126398217
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
110 KB
Volume
119
Category
Article
ISSN
0002-7863

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Large isotope effect in the quenching of
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โœ R.J. Donovan; H.M. Gillespie ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 414 KB

Spin-orbit relaxation of I(S2Pl/z)(aE = 0.94 eV) by benzene and benzende, has been studted at 297 K, using timeresolved atomic resonancefLuorescence. A large isotope effect is observed, IcC~H~ = (4.6 + 0.7) X lo-l3 cm3 molecule-' s-t, and ~C,D, = (9.9 c 1.0) X lo-l5 cm3 molecule-' s-l, despite evide