structure of Cu 4 SiP 8 contains Cu 2 pairs and a three-dimen-The title compounds were prepared in well-crystallized form sionally infinite silicon phosphorus polyanion. In CeSiP 3 from a tin flux and their crystal structure was determined (3) the cerium atoms are coordinated by nine phosphorus from
✦ LIBER ✦
Calculations of P2, P4 and P6 equilibrium distortions in the rare-earth region
✍ Scribed by Peter Möller
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 424 KB
- Volume
- 142
- Category
- Article
- ISSN
- 0375-9474
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The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 °C gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 °C produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst