Calculations of ionization rate-constants for the field-ion microscope
โ Scribed by S.C. Lam; R.J. Needs
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 60 KB
- Volume
- 277
- Category
- Article
- ISSN
- 0167-2584
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
In ICR speciroscopy rate constants for ion-molecule re;ictions arc MKIIIJ' derived from pc~~k heights. WC propose an imp~o~em&nt which WCS the total absorption intensities, which zrc independent of non-rcxtive colli=&ns;.
Vibration-vibration (V-V) exchange rate constants in nitrogen have been calculated using the integral quasiclassical representation method over a wide temperature range. Four different model intermolecular potentials arc used. Comparison with experimental data and with calculations using other semic
## The experimental evaluation of the rate constant for weak acid ionization In aqueous solution by electric field iump methods is subject to very large ermrs when pKa for the acid becomes about 6 or greater.
Experimental data concerning the effect of varying reagent vibrational, rotational and translational energy on the rates of endothermic reactions can be obtained from the application of microscopic reversibility to the corresponding exothermic processes. A 3D classical trajectory computation has bee