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Calculations of auger transitions in hydrogen fluoride

✍ Scribed by Knut Fægri Jr.

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
519 KB
Volume
46
Category
Article
ISSN
0009-2614

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✦ Synopsis

Rccelvcd 22 Novcmbcr 1976 Auger trareition cncrgrcs for hydrogen fluoride have been calculated ab initio in ;I finite basis LCGO SCIapproach. Two bnsls sets, one of double reta quahty and one cxtcnded, arc both shown to give reasonable agrcemcnt with cxpcrimental results. The effect of Cl on the (20~') tZ+ state ic dlscusscd. KL-LLL Fatelllte structure in the experimental spectrum is also accounted for by the calculations Calculatums at dlffcrcnt mternuclcar distances show that possibk contrrbutions from bond lengthcnmg arc of the same mzgmtudc as correlation effects.

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