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Calculation of the Vibrationally Resolved Electronic Absorption Spectrum of the Propargyl Radical (H 2 CCCH)

โœ Scribed by Eisfeld, Wolfgang

Book ID
127217436
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
151 KB
Volume
110
Category
Article
ISSN
1089-5639

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The vi acetylenic CH stretch of the propargyl radical (HCCCH2) near 3322 cm-' has been observed by infrared laser kinetic spectroscopy at Doppler limited resolution. Propargyl is prepared by flash photolysis of propargyl bromide or propargyl chloride at 193 nm and its transient infrared absorption p