## Abstract In the theoretical descriptions of natural and magneto‐optical activity it is customary to average classically over molecular orientations. We develop a theoretical description of the two phenomena that includes the correct quantum mechanical representation of the rotational motion in o
Calculation of the magneto–optical activity of the hydrogen molecule
✍ Scribed by E. Nørby Svendsen; Hendrik F. Hameka
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 400 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0020-7608
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📜 SIMILAR VOLUMES
The Verdet constants of the hydrogen and acetylene molecules and their dispersions as a function of wavelength were calculated by means of an ab initio STOJG molecular orbital method. The results are in good agreement with experiment.
We have calculated the rotational magnetic moment at equiiiirium nuclear distance for the hydrogen molecule by m&s of a variation-perturbation method. We obtain a vaIue of 0.89471 nuclear magnetons which should be mmp~ed with the experimental result of 0.88291 nuclw magnetons.
We use a recently proposed method to calculate the electric ~olarizabilities of the hydrogen molecule and the hydrogen molecular ion We solve the first-order and second+xder perturbation equations by variational procedures and we use the solution of the second-order perturbation equation to improve