A description of the calculation of the paramagnctrc principal suweptlbdltles for f"-clectron systems with arbitrary hgand-fields i$ gvcn.
Calculation of the Magnetic Properties ofdandfTransition Metal Complexes in Terms of the Angular Overlap Model
โ Scribed by Yu. V. Rakitin; V. M. Rakitina; V. T. Kalinnikov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2005
- Tongue
- English
- Weight
- 90 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1070-3284
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๐ SIMILAR VOLUMES
## A routine AOM analysis on the geometric isomers of bis(aspartato)cobalt complexes is performed. Contrary to assignments made on the basis of CD and NMR the AOM treatment gives the correct molecular geometries which agree with crystal structure results. the trans0, structure would be expected to
Within the framework of the angular overlap model the matrix elements of the linear Jahn-TeUer operator may easily be calculated in the weak-field basis in terms of simple operator equivalents. The method is applied to the calculation of the (MjI ~ V/~QIM'j> matrix elements for the ILS.ffvIj) ground