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Calculation of the electronic spectra and excited-state distortions of W(CO)5(N-donor) from preresonance Raman intensities

โœ Scribed by Tutt, Lee.; Zink, Jeffrey I.


Book ID
126883256
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
942 KB
Volume
108
Category
Article
ISSN
0002-7863

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Preparation, spectroscopic properties an
โœ H. Daamen; D.J. Stufkens; A. Oskam ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 565 KB

## The binuclear complexes [ {M(C0)5}21.c-pyrazine] (M = 0, W) were readily prepared by heating the mononuclear compounds in an inert atmosphere. The spectroscopic data demonstrate that the M(CO)5 moieties in these complexes have retained C,, symmetry. The two allowed metal to pyrazine CT transition