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Calculation of the effect of double bond strain in 1-chloroethylene and 1,1-dichloroethylene on the rate and mechanism of their reactions with ozone

โœ Scribed by Krisyuk, B. E.; Maiorov, A. V.; Mamin, E. A.; Popov, A. A.


Book ID
120252544
Publisher
Springer
Year
2013
Tongue
English
Weight
240 KB
Volume
54
Category
Article
ISSN
0023-1584

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Rate constants of the reaction of ozone
โœ Jian Zhang; Shiro Hatakeyama; Hajime Akimoto ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 496 KB ๐Ÿ‘ 2 views

Kinetic studies on reactions of ozone with trans-1,2-dichloroethene (DCE) and vinyl chloride (VC) were performed in air. In the presence of scavengers of radicals, such as CHBCHO, the rates for both reactions are second order (first order in each reactant). Observed rate constants are (1.80 f 0.29)