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Calculation of steric effects in reactions

✍ Scribed by DeTar, DeLos F.


Book ID
126028847
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
266 KB
Volume
96
Category
Article
ISSN
0002-7863

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Steric effects in high pressure Knoevena
✍ GΓ©rard Jenner πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 62 KB

The pressure effect in Knoevenagel condensations involving ketones and ethyl cyanoacetate is studied. The reactions are diversely affected. For cyclic ketones there is a small effect on the reaction yield. However, in the case of acyclic ketones, the sensitivity of the reaction to pressure increases