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Calculation of shear influences on the phase separation behavior of polymer solutions in the region of their lower critical solution temperature. Creation of closed miscibility gaps

โœ Scribed by Horst, R.; Wolf, B. A.


Book ID
126261960
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
493 KB
Volume
24
Category
Article
ISSN
0024-9297

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Calculation of shear influences on the p
โœ R. Horst; B. A. Wolf ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Springer-Verlag ๐ŸŒ English โš– 817 KB

Calculations were performed on the basis of a generalized Gibbs energy of mixing G~, which is the sum of the Gibbs energy of mixing of the stagnant system and Es, the energy stored in the system during stationary flow. With increasing shear rate )), the demixing temperatures shift to lower values (s