Calculation of programmed temperature retention indices: Part 2: Optimization of temperature dependence calculation
β Scribed by J. M. Santiuste
- Book ID
- 112722208
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 520 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0009-5893
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Retention temperatures of various solutes were measured on an OV-105 column under different heating rates. The experimental results agree with those evaluated by means of the equation of Curvers et al. Several methods of assigning programmedtemperature retention indices to each solute were tested. C
Direct conversion of isothermal to temperature programmed indices is not possible. In this work it is shown that linear temperature programmed retention indices can only be calculated from isothermal retention data if the temperature dependence of both the distribution coefficients and the column de
The procedure for calculating linear temperature programmed indices as described in part 1 has been evaluated using five different nonpolar columns, with OV-1 as the stationary phase. For fourty-three different solutes covering five different classes of components, including n-alkanes and alkyl-arom