𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Calculation of nuclear quadrupole splittings in microwave spectroscopy

✍ Scribed by G.O. Sørensen

Book ID
103010957
Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
235 KB
Volume
5
Category
Article
ISSN
0009-2614

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✦ Synopsis

is proposed Yobr the ca!culation of first order spIittings in rotatiunni spectra arising from interaction of rotation with the electric quadrupoie moment of one nucleus. It. is based on a J-independent relation between the patterns calculated in the case AF = AJ. I = 1 and corresponding patterns for an arbitrary spin I > 1.

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Internal rotation and chlorine nuclear q
Internal rotation and chlorine nuclear quadrupole coupling of o-chlorotoluene studied by microwave spectroscopy and ab initio calculations
✍ D. Gerhard; A. Hellweg; I. Merke; W. Stahl; M. Baudelet; D. Petitprez; G. Wlodar 📂 Article 📅 2003 🏛 Elsevier Science 🌐 English ⚖ 197 KB

The microwave spectrum of o-chlorotoluene has been reinvestigated using molecular beam Fourier transform microwave (MB-FTMW) spectrometers in the frequency range of 4-23 GHz. Due to the high resolution of this molecular beam technique the analysis yielded improved rotational constants, centrifugal d