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Calculation of Langevin-type capture rate constants for rotating molecules with arbitrary interaction potentials

✍ Scribed by Leon F. Phillips


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
552 KB
Volume
11
Category
Article
ISSN
0192-8651

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✦ Synopsis


Approximate classical trajectory calculations of capture rates are performed for collisions occurring under the influence of a combination of angle-dependent and isotropic potentials. Results calculated for a wide range of temperatures are in good accord with existing data for ion-dipole (H3+ + HCN), ionquadrupole (OH-+ C2H2), dipole-dipole (BH + NO), and dipole-quadrupole (CN + 0,) reactions.