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Calculation of Dipole Transition Matrix Elements in Muffin-Tin Models

✍ Scribed by N. A. Shilkova; V. P. Shirokovskii


Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
403 KB
Volume
146
Category
Article
ISSN
0370-1972

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We examined permanent dipole moments (PDMs) of methane-type molecules induced by molecular internal motions which are expanded in terms of the vibrational coordinate operator q, total angular momentum operator J, and vibrational angular momentum operator l. The qq-, JJ-, Jl-, and ll-type quadratic t