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Calculation and Prediction of Adsorption Excesses on the Ternary Liquid Mixture/Air Interface from Surface Tension Measurements

✍ Scribed by Grit Kalies; Peter Bräuer; Annette Schmidt; Ulf Messow


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
329 KB
Volume
247
Category
Article
ISSN
0021-9797

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✦ Synopsis


The surface tensions of the n-propanol/ethylene glycol/water ternary mixture and its binary mixtures are measured at 293 K and described by mathematical functions. The experimental data and their descriptions are shown in the three-dimensional space by means of coordinate transformation. A thermodynamic model to calculate and predict ternary adsorption excess data on the ternary liquid mixture/air interface from surface tensions is presented. The calculated adsorption excess data in the ternary triangle are discussed.