𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Calculated potential energy surfaces for the electronic states of NCNO that dissociate to the products CN(X̃ 2Σ+)+NO(X̃ 2Π)

✍ Scribed by Y.Y. Bai; G.A. Segal

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
357 KB
Volume
151
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

Ab initio configuration interaction calculations with full geometric optimization have been carried out for the electronic states of NCNO which dissociate to the ground states of CN and NO. Relative to the dissociation limit, barriers to dissociation of 2 I34 and 6986 cm-' are found for the 2 'A" and z 'A" states respectively.

📜 SIMILAR VOLUMES

Kinetic energy effects on product state
Kinetic energy effects on product state distributions in the C(3P) + N2O (X̃ 1Σ+) reaction. Energy partitioning between the NO(X 2Π) and CN(X 2Σ+) products
✍ D.C. Scott; F. Winterbottom; M.R. Scholefield; S. Goyal; H. Reisler 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 884 KB

The reaction C( 'P) +NsO(% \*C+) is studied by varying the kinetic energy of C(3P) in two center-of-mass regimes: 0.1-0.2 eV and 2-7 eV. C( 3P) is directly observed, and the C, velocity distribution is estimated from the time-of-flight of Cs. CN(X %+) is vibrationally inverted and rotationally 'hot'