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Calculated Phase Diagrams for the Electrochemical Oxidation and Reduction of Water over Pt(111)

✍ Scribed by Rossmeisl, Jan; Nørskov, Jens K.; Taylor, Christopher D.; Janik, Michael J.; Neurock, Matthew


Book ID
120428725
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
438 KB
Volume
110
Category
Article
ISSN
0022-3654

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The Electrochemical Measurement of Rate
✍ Emile Sutcliff; Michael Neumann-Spallart 📂 Article 📅 1981 🏛 John Wiley and Sons 🌐 German ⚖ 298 KB

## Abstract The appearent first‐order rate constants for the oxidation of water by iron tris (bipyridyl) (Fe (bpy)^3+^~3~), and reduction of water by methylviologen (MV^+^) catalyzed by a stabilized RuO~2~ or Pt‐sol, respectively, were measured. Rate constants for water oxidation at pH 7 of 0.4 s^−