The first electron excited Auger electron spectrum for gas-phase ammonia has been obtained and is compared with an existing theoretical prediction. Decomposition of the spectrum using a gaussian approximation rev&s close agreement in both intensity and energy for the higher energy components provide
Calculated Auger emission spectrum of ammonia
✍ Scribed by Martin T. Økland; Knut Fægri Jr.; Rolf Manne
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 314 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0009-2614
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The electron cxcitcd Auger emission ~pectrurn of munonia vapour 11~s been recorded nt various rcattermg arrglcs and analyzed. I'reviously calculated intenrity and energy of the Auger transitions arc compared with the observed qcctrunl and found in fair ngrccmcnt.
We have examtned the utdrty OC the MS Xo method of cakulatton of moieeular eleetrorue structure. in tbe transL(tonstale model, as a tool tn the analysis of valence Auger spectra, ustng CO as a test case. The method is not especiaiIy reliable tn preduztlon of ftnalstate energies, but serves reasonabl