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Calcium Peroxide Diperoxohydrate as a Storable Chemical Generator of Singlet Oxygen for Organic Synthesis

✍ Scribed by Pierlot, Christel; Nardello, Véronique; Schrive, Jordane; Mabille, Caroline; Barbillat, Jacques; Sombret, Bernard; Aubry, Jean-Marie


Book ID
120346399
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
77 KB
Volume
67
Category
Article
ISSN
0022-3263

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Dimethylsulfoxide as a kinetic booster f
✍ Marion Collinet-Fressancourt; Nathalie Azaroual; Jean-Marie Aubry; Véronique Nar 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 375 KB

The kinetic booster effect of dimethylsulfoxide on the chemical generation of singlet oxygen, 1 O 2 , from the disproportionation of hydrogen peroxide catalyzed by molybdate ions in methanol has been evidenced by detection of the IR luminescence of 1 O 2 at 1270 nm and by 95 Mo NMR spectroscopy. DMS