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Cage reactions of tertiary-butoxy radicals. Effects of viscosity and of intervening molecules

โœ Scribed by Kiefer, Hans R.; Traylor, Teddy G.


Book ID
127100345
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
548 KB
Volume
89
Category
Article
ISSN
0002-7863

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Reactions of primary and secondary butox
โœ A. Heiss; J. Tardieu De Maleissye; V. Viossat; K. A. Sahetchian; I. G. Pitt ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 838 KB

The reaction pathways of n-butoxy and s-butoxy radicals have been investigated by TLC and HPLC analysis of end products, particularly peroxides and carbonyl compounds. The butoxy radicals were produced by the pyrolysis of very low concentrations of the corresponding dibutylperoxide in an atmosphere