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(C6H5Sb)6·(1,4-dioxane), the First Cyclohexastibane

✍ Scribed by Priv.-Doz. Dr. Hans Joachim Breunig; Dipl.-Chem. Karl Häberle; Prof. Dr. Martin Dräger; Dipl.-Chem. Tevfik Severengiz


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
250 KB
Volume
24
Category
Article
ISSN
0044-8249

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Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi