C60 as a stationary phase for microcolumn liquid chromatographic separation of polycyclic aromatic hydrocarbons
β Scribed by Kiyokatsu Jinno; Kunihiko Yamamoto; John C. Fetzer; Wilton R. Biggs
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 280 KB
- Volume
- 4
- Category
- Article
- ISSN
- 1040-7685
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β¦ Synopsis
Abstract
Buckminsterfullerene C~60~ was evaluated as a stationary phase for the microcolumn liquid chromatographic separation of polycyclic aromatic hydrocarbons. Material prepared from a soot extract was packed into a fusedβsilica capillary, 13βmm times; 0.53βmm i. d. The chromatographic characteristics were examined. The results indicate that C~60~ can work as a liquid chromatographic stationary phase, offering a unique shape selectivity for polycyclic aromatic hydrocarbons compared with octadecylsilica and dicoronylene stationary phase.
π SIMILAR VOLUMES
## Abstract A chemically bonded C~60~ silica phase was synthesized as a stationary phase for liquid chromatography (LC) and its retention behavior evaluated for various polycyclic aromatic hydrocarbons (PAHs) using microcolumn LC. The results indicate that the C~60~ bonded phase offers selectivity
## Abstract Modern liquid chromatographic (LC) conditions which effect a separation of polycyclic aromatic hydrocarbons (PAH) containing up to ten rings are described. The LC conditions include reverseβphase chromatographic columns in combination with a quaternary solvent system. Methanol and water
A novel chemically bonded phase was evaluated for its applicability in Ε½ . discriminating among polycyclic aromatic hydrocarbons PAHs in terms of molecular size, planarity, and shape selectivity. It was observed that planar molecules were more retained than nonplanar analogues and that the retention