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C5H9O2+ ions: the correlation between their thermochemistry in acidic solution and their chemistry in the gas phase

✍ Scribed by Asensio, Gregorio; Miranda, Miguel A.; Perez-Prieto, Julia; Sabater, Maria J.; Simon-Fuentes, Antonio

Book ID: 126295135
Publisher: American Chemical Society
Year: 1992
Tongue: English
Weight: 576 KB
Volume: 57
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00049a029

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## Abstract A mechanistically unprecedented situation characterizes the gas‐phase ion chemistry of Ni(C,H~3~,O)^+^ when reacted under thermal, single‐collision conditions with ethane. A dehydrogenation channel leading to Ni(C~3~,H~7~,O)^+^ is to 90% preceded by a complete loss of positional identit