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(C5H16N2)× [Zn3(HPO3)4]×H2O: A New Three-Dimensional Zincophosphite with 12-Membered Ring Channels and Infinite Edge Shared 4-Membered Ring Ladders.

✍ Scribed by Lei Wang; Hong Ding; Ying Hou; Linlin Zhu; Zhan Shi; Shouhua Feng

Publisher
John Wiley and Sons
Year
2006
Weight
10 KB
Volume
37
Category
Article
ISSN
0931-7597

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Hydrothermal Synthesis and Crystal Structure of Zn4(PO4)2(HPO4)2·0.5(C10H28N4)·2H2O, a New Layered Zinc Phosphate with 12-Ring Cavities
✍ Ping Zhang; Yue Wang; Guangshan Zhu; Zhan Shi; Yunling Liu; Hongming Yuan; Wenqi 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 232 KB

Using 1, 4, 8, 11-tetraazacyclotetradecane (cyclam) as a template, a new layered zinc phosphate Zn 4 (PO 4 ) 2 (HPO 4 ) 2 ' 0.5(C 10 H 28 N 4 ) ' 2H 2 O (de5ned as ZnPO-cyclam) with 12-ring cavities was synthesized under hydrothermal conditions in a molar ratio ZnO:P 2 O 5 :cyclam:H 2 O ‫؍‬ 1:2.2:0.