𝔖 Bobbio Scriptorium
✦   LIBER   ✦

(C4H14N2)2[Mo8O26]·2H2O: a new molybdate salt

✍ Scribed by Thorn, Katherine J. ;Narducci Sarjeant, Amy ;Norquist, Alexander J.


Book ID
104484829
Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
289 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


Crystals of the title compound, 2-(dimethylammonio)ethanaminium hexacosaoxaoctamolybdate(VI) dihydrate, containing extended chains constructed from centrosymmetric octamolybdate anions, were grown under mild hydrothermal conditions in the presence of N,N-dimethylethylenediamine. An extensive hydrogen-bonding network helps stabilize the crystal structure.


📜 SIMILAR VOLUMES


(C6H16N2)2[Mo8O26]: a new β-octamolybdat
✍ Muller, Eric A. ;Sarjeant, Amy Narducci ;Norquist, Alexander J. 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 171 KB

dimethylpiperazinediium -octamolybdate, were grown under mild hydrothermal conditions. The anion and cations lie on inversion centers. A network of N-HÁ Á ÁO bonds helps to stabilize the crystal packing.

A New Octamolybdate: (NH4)6Mo8O26(OH)2·2
✍ Prof. Dr. Oskar Glemser; Dipl.-Chem. Gebhard Wagner; Priv.-Doz. Dr. Bernt Krebs 📂 Article 📅 1970 🏛 John Wiley and Sons 🌐 English ⚖ 140 KB 👁 1 views
Synthesis, characterization and crystal
✍ M. Grzywa; W. Nitek; W. Łasocha 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 526 KB

The crystal structures of three dinuclear diperoxo compounds have been determined from single-crystal X-ray diffraction data. All title compounds crystallize as yellow needle-shaped crystals in the triclinic space group P 1(2). ( 1 where 2-MepyH denotes 2-methylopyridine, crystallize with a = 6.733