dimethylpiperazinediium -octamolybdate, were grown under mild hydrothermal conditions. The anion and cations lie on inversion centers. A network of N-HÁ Á ÁO bonds helps to stabilize the crystal packing.
(C4H14N2)2[Mo8O26]·2H2O: a new molybdate salt
✍ Scribed by Thorn, Katherine J. ;Narducci Sarjeant, Amy ;Norquist, Alexander J.
- Book ID
- 104484829
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 289 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Crystals of the title compound, 2-(dimethylammonio)ethanaminium hexacosaoxaoctamolybdate(VI) dihydrate, containing extended chains constructed from centrosymmetric octamolybdate anions, were grown under mild hydrothermal conditions in the presence of N,N-dimethylethylenediamine. An extensive hydrogen-bonding network helps stabilize the crystal structure.
📜 SIMILAR VOLUMES
The crystal structures of three dinuclear diperoxo compounds have been determined from single-crystal X-ray diffraction data. All title compounds crystallize as yellow needle-shaped crystals in the triclinic space group P 1(2). ( 1 where 2-MepyH denotes 2-methylopyridine, crystallize with a = 6.733