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C45- and C50-Carotinoide. 1. Mitteilung. Synthese von (R)- and (S)-Lavandulol

✍ Scribed by Andreas Kramer; Hanspeter Pfander

Publisher: John Wiley and Sons
Year: 1982
Tongue: German
Weight: 524 KB
Volume: 65
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19820650132

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✦ Synopsis

C~45~‐ and C~50~‐Carotenoids, 1st Communication. Synthesis of (R)‐ and (S)‐Lavandulol

Starting with methyl (3 R)‐3‐hydroxybutanoate ((R)‐7) and ethyl (3 S)‐3‐ hydroxybutanoate ((S)‐11), respectively, (R)‐ and (S)‐lavandulol ((R)‐1 and (S)‐1) were synthesized with high optical purity. The synthesized key intermediates (R)‐6 and (S)‐6 are suitable compounds for the synthesis of optically active acyclic C~45~‐ and C~50~‐carotenoids.

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