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C2-Symmetric Bis-sulfoxides: Synthesis of Both Enantiomers and Utilization in Organometallic Chemistry and in Asymmetric Catalysis

✍ Scribed by Inmaculada Fernandez; Cristina S. Araujo; Felipe Alcudia; Noureddine Khiar


Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Synthesis of novel C2-symmetrical chiral
✍ Miyuki Ishizaki; Osamu Hoshino πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 92 KB πŸ‘ 2 views

## Abstract Novel C~2~‐symmetrical chiral sulfides were synthesized from (__R,R__)‐tartaric acid and their utility in the asymmetric epoxidation of aldehydes with benzyl bromide was examined. Among the sulfides used, silyl ether‐type sulfides were found to be superior to diol‐ and benzyl ether‐type