C1–C4hydrocarbon release in the preparation of SiF4through Na2SiF6pyrolysis
✍ Scribed by V. A. Krylov; T. G. Sorochkina; A. D. Bulanov; A. Yu. Lashkov
- Book ID
- 110167170
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2011
- Tongue
- English
- Weight
- 161 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0020-1685
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An __in situ__ X-ray powder diffraction study has shown the cubic modification of (NH~4~)~2~SiF~6~ (cryptohalite, space group __Fm__¯3__m__) at 0.2–0.3 GPa to transform irreversibly into the trigonal bararite, space group __P__¯3__m__1. The anisotropy of lattice strain in the high-pressure phase of
The infrared multiphoton decomposition of Si2F 6 has been investigated by time-resolved infrared diode laser spectroscopy. Direct formation of SiF2 ()(IA~) in the ground vibrational state and indirect formation via vibrational relaxation were found. Simultaneous formation of SiF4 with SiF2 was also