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C-nucleosides and related compounds. Synthesis of D,L-3,4- isopropylidene-2,5-anhydroallose: a novel periodate cleavage

✍ Scribed by George Just; Alain Martel

Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 179 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95986-6

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✦ Synopsis

The synthesis of C-nucleosldes requires intermediates of type XIV, XVI2 , XVII or XVIII 3,4 which are as yet not too readily available.

Olefin XIII held promrse as a precursor for such intermedrates and we therefore set out to synthesize It.

Brcyclic acid I', obtarned by standard reactions from known precursors 6,7 , was submitted to an oxldative decarboxylation reaction*.

Only the corresponding anhydrlde was recovered from the reactlon mixture.

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