## Abstract The reaction of α‐chloronitrosoalkanes with aliphatic and aromatic Grignard reagents RMgX has been studied using the model compound α‐chloronitrosoadamantane (AdClNO)1. In addition to adamantanone oxime 7 (4‐60%) and the adamantanone oxime ether 8 (trace −28%), the expected nitrone 2 is
C-Nitroso compounds. Part XXXVII. The reactivity of α-chloronitroso compounds towards organoaluminium reagents
✍ Scribed by J. Lub; M. L. Beekes; Th. J. de Boer
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 609 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0165-0513
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## Abstract The α‐chloronitroso compounds **1a–1f** were made to react with methyl and phenyl Grignard reagents. N‐methyl and N‐phenyl substituted ketonitrones **2** and **3** were obtained in 48‐78% yield. The structure of these labile nitrones is based on their spectroscopic properties and on the
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