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C-nitroso compounds. Part V. The preparation of cis-azodioxy compounds (cis-dimeric nitroso compounds)

✍ Scribed by A. Mackor; Th.A.J.W. Wajer; Th.J. de Boer

Publisher: Elsevier Science
Year: 1967
Tongue: French
Weight: 271 KB
Volume: 8
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)90853-0

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✦ Synopsis

Nitroso compounds are known to exist in monomeric and dimeric forms, which are in equilibrium in solution:

colourless blue Solutions of tertiary nitroso-dimers are blue, owing to considerable dissociation.

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## Nitrosoalkanes possess free-radical scavenging properties. The reaction with alkylradicals has been shown to proceed via diallrylnitroxides, stable free radicals with