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C-Glycosides V: Données mécanistiques sur l'halogénation d'hydrazones et d'oximes dérivées de sucres. Communication préliminaire

✍ Scribed by J. M. J. Tronchet; Br. Baehler; N. Le-Hong; P. F. Livio

Publisher
John Wiley and Sons
Year
1971
Tongue
German
Weight
386 KB
Volume
54
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The bromination of aldehydo‐sugars p‐nitrophenylhydrazones has been studied and the gem‐bromo‐azo intermediates isolated and characterized in some cases. In the same way, in the chlorination of aldehydo‐sugars oximes gem‐chloro‐nitroso intermediates have been obtained and in some instances isolated. These observations support a S~E~2′ mechanism for such reactions.

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