In this work, the high-resolution infrared (IR) spectrum of \({ }^{13} \mathrm{C}\)-substituted methyl alcohol corresponding to the \(\mathrm{C}-\mathrm{O}\) stretch vibration and the far-infrared (FIR) spectrum corresponding to the torsional-rotational transitions have been recorded using a Fourier
C-13 Methanol Far-Infrared Laser: Newly Discovered Lines, Predictions, and Assignments
โ Scribed by E.C.C. Vasconcellos; S.C. Zerbetto; L.R. Zink; K.M. Evenson; R.M. Lees; Li-Hong Xu
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 119 KB
- Volume
- 188
- Category
- Article
- ISSN
- 0022-2852
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โฆ Synopsis
We report 25 new laser lines from 13 CH 3 OH methanol when pumped by a cw CO 2 laser. The majority of the lines are pumped by the 10R (regular) and 10SR (sequence) bands of the CO 2 laser. Two are pumped by the 9HP(20) hotband CO 2 line. We measured 22 laser frequencies in this molecule, 19 from new lines and three from previously reported lines. We also remeasured and corrected the frequency of the 9P(44) pumped line as 3 378 404.87 MHz (88.738 mm). We assigned two lines-10SR(17), 77.5758 cm 01 and 10R(50), 119.3020 cm 01 -and predicted other potential farinfrared laser lines with these two pumps.
๐ SIMILAR VOLUMES
A "LaseRitz" program is described for the systematic assignment and prediction of far-infrared laser (FIRL) transitions for a given molecule, such as methanol or hydrazine, which can be generated by optical pumping with known laser lines. The input data set for the program consists of identified mol