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Buzonamine, a new alkaloid from the defensive secretion of the millipede, Buzonium crassipes

โœ Scribed by William F. Wood; Frederick J. Hanke; Isao Kubo; Jennifer A. Carroll; Phillip Crews

Book ID
114232034
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
118 KB
Volume
28
Category
Article
ISSN
0305-1978

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โœ Kenji Mori; Yasuyo Takagi ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 105 KB

Asymmetric Michael addition of the enamine derived from 2,2-dimethylcyclopentanecarboxaldehyde and (S)-prolinol methyl ether to nitroethylene aorded the adduct of 76% ee, which ยฎnally yielded enantiomerically pure (+)-polyzonimine and (+)-nitropolyzonamine, compounds from the defensive glands of a m