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Butyllithium-induced dimerization of pent-3-en-1-yne and related additions

✍ Scribed by P.A.A. Klusener; H. Hommes; J.C. Hanekamp; A.C.H.T.M. van der Kerk; L. Brandsma


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
947 KB
Volume
409
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES


Addition of lithium metal to but-1-en-3-
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But-1-en-3-ynes react with lithium and chlorotrimethylsilane in THF to give 1,4-bis(trimethylsilyl)buta-2,3dienes. Epoxidation of these allenes leads to oxyallyl species which are trapped by nucleophilic reagents to give 1,4-bis(trimethylsilyl)butan-3-ol-2-one derivatives.

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