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Butadiene–styrene copolymerization initiated by n-BuLi/THF/t-AmOK

✍ Scribed by Bu Lehong; Ying Shengkang


Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
492 KB
Volume
44
Category
Article
ISSN
0021-8995

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Styrene-butadiene copolymerization initi
✍ Boris I. Nakhmanovich; Alexander A. Arest-Yakubovich; Tatyana N. Prudskova; Gali 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 273 KB

The following values of monomer reactivity ratios were found: rs = 3,3 f 0,3; rB = 0,12 i 0,02 (cyclohexane, 25 "C). The comparison of the kinetic parameters obtained with Li, Na and K counter-ions shows that the great difference between coordination polymerization with Li and "typically anionic" po