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Butadiene Hydroamination with Aqueous Ammonia Catalyzed by Palladium(II) Sulfoxide Complexes.

✍ Scribed by U. M. Dzhemilev; G. A. Tolstukov; R. I. Khusnutdinov; N. A. Shchadneva; A. R. Baiguzina; T. M. Oshnyakova; L. F. Mukhametshina


Publisher
John Wiley and Sons
Year
2007
Weight
22 KB
Volume
38
Category
Article
ISSN
0931-7597

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Reaction of aminoalcohols with butadiene
✍ J. David Umpleby πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 German βš– 160 KB

## Abstract The aminoalcohols **1**, react with 2 equivalents of butadiene in the presence of catalytic quantities of bis (acetylacetonato)palladium/triphenylphosphine to give exclusively the corresponding __N__‐octadienyl amninoalcohols. In the presence of excess butadiene, subsequent __O__‐octadi