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Bulky substituent effects on the iron(III) complexation of 1,4,7-triazacyclononane

✍ Scribed by Jonathan L. Sessler; John W. Sibert; Vincent Lynch

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
717 KB
Volume
216
Category
Article
ISSN
0020-1693

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The complexation of iron(iii) chloride with 1,4,7-tris[3,4-bis(decyloxy)benzyl]-1,4,7-triazacyclononane leads to a liquid crystalline product, which forms a second mesophase after thermal treatment at around 70 8C above the first clearing temperature. Polarizing microscopy, DSC, and UV observations