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Bulky Diphosphite-Modified Rhodium Catalysts: Hydroformylation and Characterization

✍ Scribed by van Rooy, Annemiek; Kamer, Paul C. J.; van Leeuwen, Piet W. N. M.; Goubitz, Kees; Fraanje, Jan; Veldman, Nora; Spek, Anthony L.

Book ID
120215223
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
455 KB
Volume
15
Category
Article
ISSN
0276-7333

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Solution structures of hydrido-rhodium d
Solution structures of hydrido-rhodium diphosphite hydroformylation catalysts
✍ Piet W. N. M. van Leeuwen; Godfried J. H. Buisman; Annemiek van Rooy; Paul C. J. πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 205 KB

## Abstract The NMR spectroscopy data for five hydroformylation catalysts RhH(CO)~2~(P‐P) (P‐P = diphosphite bidentate ligand) are reported and interpreted in terms of equatorial and axial coordination of the phosphorus and carbon monoxide ligands in a trigonal bipyramidal structure.