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Bulk Crystallization Kinetics of Metallocene Polyethylenes with Well-controlled Molecular Weight and Short Chain Branch Content

✍ Scribed by Fang-Chyou Chiu; Ya Peng; Qiang Fu


Book ID
110407437
Publisher
Springer
Year
2002
Tongue
English
Weight
139 KB
Volume
9
Category
Article
ISSN
1022-9760

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πŸ“œ SIMILAR VOLUMES


Crystallization and morphology of metall
✍ Ya Peng; Qiang Fu; Fang-Chyou Chiu πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 370 KB

## Abstract The crystallization and morphology of some metallocene polyethylenes with well‐controlled molecular weight and branching content were investigated by DSC, WAXD, PLM and SALS. The banded spherulites observed in linear PE are not seen in crystallization of branched PEs. The small spheruli

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Full Paper: Copolymerization of ethylene and 1-hexene was carried out with different catalysts: homogeneous Et[Ind] 2 ZrCl 2 , Cp 2 HfCl 2 and [(C 5 Me 4 )SiMe 2 N(tert-Bu)]TiCl 2 , the corresponding in-situ supported metallocenes, and combined in-situ supported metallocene catalysts (mixtures of Et