## Abstract The crystallization and morphology of some metallocene polyethylenes with wellβcontrolled molecular weight and branching content were investigated by DSC, WAXD, PLM and SALS. The banded spherulites observed in linear PE are not seen in crystallization of branched PEs. The small spheruli
β¦ LIBER β¦
Bulk Crystallization Kinetics of Metallocene Polyethylenes with Well-controlled Molecular Weight and Short Chain Branch Content
β Scribed by Fang-Chyou Chiu; Ya Peng; Qiang Fu
- Book ID
- 110407437
- Publisher
- Springer
- Year
- 2002
- Tongue
- English
- Weight
- 139 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1022-9760
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Full Paper: Copolymerization of ethylene and 1-hexene was carried out with different catalysts: homogeneous Et[Ind] 2 ZrCl 2 , Cp 2 HfCl 2 and [(C 5 Me 4 )SiMe 2 N(tert-Bu)]TiCl 2 , the corresponding in-situ supported metallocenes, and combined in-situ supported metallocene catalysts (mixtures of Et