Bulk and Interfacial Properties for CO2-SO2 Binary Mixtures

✍ Scribed by Dong Fu; Jiazi Feng; Jianyi Lu

• Publisher: John Wiley and Sons
• Year: 2010
• Tongue: English
• Weight: 216 KB
• Volume: 28
• Category: Article
• ISSN: 0256-7660
• DOI: 10.1002/cjoc.201090314

✦ Synopsis

The perturbed-chain statistical associating fluid theory (PC-SAFT) and density-gradient theory (DGT) were used to construct an equation of state (EOS) for the phase behaviors of carbon dioxide (CO 2 )-sulfur dioxide (SO 2 ) binary mixtures. The p-x diagrams at 263 and 333 K, and the p-T diagrams corresponding to 2 CO x ＝0.8871 and 0.6213 were satisfactorily calculated as compared to the experimental data. With the influence parameters of pure components and the equilibrium bulk properties of mixtures as input, the interfacial properties of CO 2 -SO 2 binary mixtures in a wide temperature range were predicted, and the influences of temperature, pressure and bulk properties on the surface tension were discussed.